Bq. Chen et Jx. Wen, SYNTHESIS AND MESOGENIC PROPERTIES OF ALKOXYPHENYL-2,3,5,6-TETRAFLUOROPHENYL)-BUTADIYNES, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 289, 1996, pp. 141-148
Three series of 1,4-disubstituted butadiynes containing a tetrafluorop
henylene in core structure have been synthesized from 1-pentafluorophe
nyl-2-trimethylsilyacetylene. The results showed that alkoxyphenyl-2,3
,5,6-tetrafluorophenyl)-butadiynes were nematic liquid crystals. Howev
er, (4-n-alkoxy-2,3,5,6-tetrafluoro-phenyl)-butadiynes and (4-n-alkoxy
-2,3,5,6-tetrafluorophyenyl)-butadiynes did not exhibit any liquid cry
stallinity. The IR spectra showed that the l-phenyl-C(4-n-alkoxyphenyl
-2,3,5, 6-tetrafluorophenyl)-butadiynes were good liquid crystals for
IR modulator.