M. Mansori et al., PHASE-DIAGRAM IN THE (BI,PB)-SR-CA-CU-O SYSTEM - INFLUENCE OF PARTIALCONSTRAINT OXYGEN-PRESSURE, Physica. C, Superconductivity, 235, 1994, pp. 331-332
DTA-DTG, X ray diffraction and metallographic measurements at differen
t temperatures and partial oxygen pressure in the isoplethic cut ''(Bi
,Pb)(2)Sr2CuOx-CaCuO2'', were carried out to analyze the influence of
partial constraint oxygen pressure on phase transformations. An isobar
ic invariant equilibrium has been found in the Po-2 range 0.5-1. Suppl
ementary phase appearing at invariant equilibrium is (Sr,Ca)(3)Cu5Oy.
That phase fixes oxygen and then the weight loss is stopped.