Sg. Eriksson et al., THE INFLUENCE OF DOPANT IONS ON STRUCTURE AND PROPERTIES IN TL-1212 AND TL-2212, Physica. C, Superconductivity, 235, 1994, pp. 541-542
By changing the Y/Ca ratio in Tl-1212 and Tl-2212 structure as well as
properties alter. At a certain dopant level a discontinous change in
atomic structure, T-c, Raman phonon modes and in Tl-205 NMR Knight shi
ft occur. We have also shown that La3+ or Sr2+ substitution at the Ba
site, oxygen depletion, or insertion of hydrogen in the Tl-2212 materi
al affect structure and carrier concentration and thus T-c.