Bixbyite type Y2O3:Eu3+ apart from being the efficient red phosphor ex
tensively used in trichromatic fluorescent lamps, it is a typical syst
em one can apply Jorgensen's refined electron spin pairing theory. Thi
s can be used to explain the enhancement in Eu3+ emission intensity ob
served with the aliovalent substitution in the yttria host matrix. Res
ults based on these are explained qualitatively by considering a simpl
e configurational coordinate model. Futhermore, an insight into the di
fferent types of defects induced with the aliovalent substitution in t
he yttria lattice has become possible with EPR probe.