LIPOPHILIC LANTHANIDE COMPLEXES - A NEW CLASS OF CARRIERS FOR EXTRACTION AND TRANSPORT OF POTASSIUM BENZYLOXYCARBONYLAMINO ACIDATES

Authors
TSUKUBE H SHIBA H UENISHI J
Citation
H. Tsukube et al., LIPOPHILIC LANTHANIDE COMPLEXES - A NEW CLASS OF CARRIERS FOR EXTRACTION AND TRANSPORT OF POTASSIUM BENZYLOXYCARBONYLAMINO ACIDATES, Journal of the Chemical Society. Dalton transactions, (2), 1995, pp. 181-184
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
2
Year of publication
1995
Pages
181 - 184
Database
ISI
SICI code
0300-9246(1995):2<181:LLC-AN>2.0.ZU;2-G
Abstract
Lipophilic lanthanide complexes co-ordinated by fluorinated beta-diket one ligands [M(OCRCHCR'O)(3)] (M = Eu, Pr, Dy or Yb; R = Bu(t), R' = C 3F7 or CF3) were demonstrated to act as neutral carriers for efficient extraction and rapid transport of potassium benzyroxycarbonylamino ac idates. They formed 1:1 complexes with the organic anions and exhibite d different anion-extraction and transport behaviours from those of co mmon anion carriers.