ORGANOMETALLIC LIQUID-CRYSTALS BASED ON OCTAHEDRAL RHODIUM(III)

Authors
ROURKE JP BRUCE DW MARDER TB
Citation
Jp. Rourke et al., ORGANOMETALLIC LIQUID-CRYSTALS BASED ON OCTAHEDRAL RHODIUM(III), Journal of the Chemical Society. Dalton transactions, (2), 1995, pp. 317-318
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
2
Year of publication
1995
Pages
317 - 318
Database
ISI
SICI code
0300-9246(1995):2<317:OLBOOR>2.0.ZU;2-0
Abstract
Reaction of mesomorphic alkynes with [RhMe(PMe(3))(4)] led to the Rh-I II complexes mer,trans-[RhH(alkynyl)(2)(PMe(3))(3)] which are liquid c rystalline; they are rare examples of rod-like liquid crystals based o n an octahedral metal centre and represent a unique homologous series of mesomorphic metal complexes containing a hydride function.