SYNTHESIS OF [AU(NH3)(2)](-STRUCTURE OF [AU(NH3)(2)]BR() SALTS AND THE CRYSTAL)

Authors
MINGOS DMP YAU J MENZER S WILLIAMS DJ
Citation
Dmp. Mingos et al., SYNTHESIS OF [AU(NH3)(2)](-STRUCTURE OF [AU(NH3)(2)]BR() SALTS AND THE CRYSTAL), Journal of the Chemical Society. Dalton transactions, (2), 1995, pp. 319-320
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
2
Year of publication
1995
Pages
319 - 320
Database
ISI
SICI code
0300-9246(1995):2<319:SO[O[S>2.0.ZU;2-H
Abstract
The complexes [Au(NH(2)R)(2)]X (R = H, Me, Et or Bu(t); X = Br, SbF6 o r BF4) have been synthesised and characterised by IR, NMR spectra and by thermal gravimetric and differential scanning calorimetry technique s; the single-crystal structural determination of [Au(NH3)(2)]Br has c onfirmed the linear co-ordination about gold and highlighted some inte resting bond-length differences compared to [Ag(NH3)(2)]NO3.