We report measurements of the dynamic resistance of a de-SQUID formed
by two contacts between two different edges of a single crystal of YBa
2Cu3O6.9 and a Nb block. The phase of the field induced RD oscillation
s was compared with those of two adjacent SQUIDs, each formed by two N
b-Nb contacts. We find a phase difference of 160+/-30 degrees between
the oscillations of the composite SQUID and those of the SQUIDs formed
by Nb-Nb junctions. A possible explanation for this reproducible effe
ct is that the cuprate superconductor has an unconventional order para
meter.