PARTICLE-INDUCED-GAMMA-RAY-EMISSION SPECTROMETRY APPLIED TO THE DETERMINATION OF LIGHT-ELEMENTS IN INDIVIDUAL GRAINS OF GRANITE MINERALS

The quantitative determination of Li, Be, B, F is feasible using a sen sitive and non-destructive method by the analysis of the prompt gamma- rays induced with charged particles (PIGE). The irradiation source is a Van de Graaff accelerator, and gamma-analysis has to be performed du ring the irradiation. Measurements were made at the CERI laboratory in Orleans with the PIGE method using a 100 x 300 mu m(2) focused beam o f 3 MeV alpha particles. Among the applications, micas along a drill c ore from the Beauvoir granite were analyzed. Bulk analyses of light el ements in the drill core have previously been made. Coarse-grained mic as were selected, individually irradiated and directly analyzed in pol ished thin sections from different elevations in the drill core. The s ensitivity depends on the cross-sections of the nuclear reactions, on the particle current and on the duration of the irradiation. With a pa rticle current irradiation of 25 nA during 1000 seconds, a 20 ppm limi t of detection is reached for Be, 25 ppm for Li, 900 ppm for B and 450 ppm for F. A large variation of Be contents in the micas was found at equal drill hole elevations, and there was no strong correlation betw een whole-rock compositions and the mineral chemistry. The latter have been determined both by PIGE and by mineral separation and ICP analys es. On the other hand, a strong Li-F correlation was observed between the fluor-polylithionite and muscovite end-members, supporting previou s analyses from equal elevation wells on sorted micas. Be-Li correlati on is poorly defined, but the contents of the micas analyzed remained between the contents of bityite (Be-Li bearing mica) and lepidolites ( Li-bearing micas) end-members. This suggests a solid-solution between the end-members, the extent of which is very narrow because the Be con tents were not higher than 500 ppm. The detection limit is a function of the spatial resolution, because the current of the incident alpha ( or p) particles decreases with the impact size. The results show that the analysis of small individual grains of minerals with PIGE can thus be complementary to other analytical methods such as the electronic m icroprobe.