Calgd. Forbicini et Bf. Dearaujo, ELECTROCHEMICAL PROCEDURES IN THE TREATMENT OF SPENT NUCLEAR-FUEL, Journal of radioanalytical and nuclear chemistry, 185(2), 1994, pp. 331-346
The use of an electrochemical process for U/Pu partitioning has demons
trated a good performance and is a safe alternative for nuclear facili
ties. Its great advantages are the lack of introduction of foreign ion
s into the process and, especially, the minimization of the waste volu
me generated. For the introduction of electrochemical U/Pu partitionin
g in the 2nd Pu purification cycle, preliminary studies were carried o
ut with a single mixer-settler unit, Based on the results, an 8-stage
electrolytic mixer-settler (MS MIRELE) was designed. Titanium was MIRE
LE's housing material(cathode) and platinum the anode, insulated with
PTFE. The Pu recovery was higher than 99%, indicating the efficiency o
f this equipment.