ELECTROCHEMICAL PROCEDURES IN THE TREATMENT OF SPENT NUCLEAR-FUEL

Citation
Calgd. Forbicini et Bf. Dearaujo, ELECTROCHEMICAL PROCEDURES IN THE TREATMENT OF SPENT NUCLEAR-FUEL, Journal of radioanalytical and nuclear chemistry, 185(2), 1994, pp. 331-346
Citations number
13
Categorie Soggetti
Chemistry Analytical","Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
ISSN journal
02365731
Volume
185
Issue
2
Year of publication
1994
Pages
331 - 346
Database
ISI
SICI code
0236-5731(1994)185:2<331:EPITTO>2.0.ZU;2-5
Abstract
The use of an electrochemical process for U/Pu partitioning has demons trated a good performance and is a safe alternative for nuclear facili ties. Its great advantages are the lack of introduction of foreign ion s into the process and, especially, the minimization of the waste volu me generated. For the introduction of electrochemical U/Pu partitionin g in the 2nd Pu purification cycle, preliminary studies were carried o ut with a single mixer-settler unit, Based on the results, an 8-stage electrolytic mixer-settler (MS MIRELE) was designed. Titanium was MIRE LE's housing material(cathode) and platinum the anode, insulated with PTFE. The Pu recovery was higher than 99%, indicating the efficiency o f this equipment.