RECOIL CHLORINE REACTIONS WITH ETHYLENE

Authors
CHAO JH LO JG
Citation
Jh. Chao et Jg. Lo, RECOIL CHLORINE REACTIONS WITH ETHYLENE, Journal of radioanalytical and nuclear chemistry, 185(2), 1994, pp. 355-367
Citations number
9
Categorie Soggetti
Chemistry Analytical","Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
185
Issue
2
Year of publication
1994
Pages
355 - 367
Database
ISI
SICI code
0236-5731(1994)185:2<355:RCRWE>2.0.ZU;2-C
Abstract
The reactions of re:coil Cl-38 atoms produced through the Cl-37(n, gam ma)Cl-38 process in the CF3Cl-C2H4 gas phase are described in this wor k, The CF3Cl is a chlorine source as well as moderator. Scavengers, su ch as O-2 and H2S, were added to the system to discriminate the reacti ons induced by energetic and/or thermal chlorine atoms. The radioactiv e Cl-38-labeled products were separated using gas-chromatographic tech nique followed by an external proportional counter for quantitative de termination of the product yields. The mechanisms of the chemical reac tions are predicted to account for the formation of these organic comp ounds.