RESOLUTION OF RACEMIC CARBOXYLIC AND SULFONIC-ACIDS VIA D-XYLOSE DERIVED NEW CYCLIC CARBAMATE REAGENTS (OXAZOLIDIN-2-ONES)

Authors
KOLL P LUTZEN A
Citation
P. Koll et A. Lutzen, RESOLUTION OF RACEMIC CARBOXYLIC AND SULFONIC-ACIDS VIA D-XYLOSE DERIVED NEW CYCLIC CARBAMATE REAGENTS (OXAZOLIDIN-2-ONES), Tetrahedron : asymmetry, 6(1), 1995, pp. 43-46
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
1
Year of publication
1995
Pages
43 - 46
Database
ISI
SICI code
0957-4166(1995)6:1<43:RORCAS>2.0.ZU;2-Y
Abstract
Two new chiral oxazolidin-2-ones have been easily prepared from D-xylo se and studied as chiral derivatizing agents (CDA's) for the resolutio n of racemic carboxylic and sulfonic acids The resultant diastereomers are readily separated by chromatographic methods and easily hydrloyze d to isolate the resolved materials in high optical purities and to re turn the CDA's for reuse.