STEREOSELECTIVE SYNTHESIS OF DI-BETA-D-FRUCTOPYRANOSE 1,2' 2,1'-DIANHYDRIDE, A SPIRODIOXANYL PSEUDODISACCHARIDE WITH METAL CATION COMPLEXING PROPERTIES/

Authors
FERNANDEZ JMG SCHNELLE RR DEFAYE J
Citation
Jmg. Fernandez et al., STEREOSELECTIVE SYNTHESIS OF DI-BETA-D-FRUCTOPYRANOSE 1,2' 2,1'-DIANHYDRIDE, A SPIRODIOXANYL PSEUDODISACCHARIDE WITH METAL CATION COMPLEXING PROPERTIES/, Tetrahedron : asymmetry, 6(1), 1995, pp. 307-312
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
1
Year of publication
1995
Pages
307 - 312
Database
ISI
SICI code
0957-4166(1995)6:1<307:SSOD12>2.0.ZU;2-L
Abstract
A stereoselective synthesis of di-beta-D-fructopyranose 1,2':2,1'-dian hydride by protonic activation of 2,3:4,5-di-O-isopropylidene-beta-D-f ructopyranose with anhydrous hydrogen fluoride is reported. The reacti on involves the formation of 1,3:4,5-di-O-isopropylidene-beta-D-fructo pyranosyl fluoride as isolable intermediate.