Hq. Mao et al., STUDIES ON THE PHOSPHORYLATING POLYCONDENSATION CATALYZED BY 4-DIMETHYLAMINOPYRIDINE, Macromolecular chemistry and physics, 196(2), 1995, pp. 655-658
The phosphorylating polycondensation in solution catalyzed by 4-dimeth
ylaminopyridine (DMAP) was studied for the first time. The polymerizat
ion rate and the average molecular weight of the polyphosphate are inc
reased by using DMAP as a catalyst. The influence of reaction conditio
ns on the catalytic activity of DMAP were preliminarily investigated.