FE-57 MOSSBAUER-SPECTROSCOPY STUDY OF EU1-XCAXFEO3-Y

Citation
Lp. Li et al., FE-57 MOSSBAUER-SPECTROSCOPY STUDY OF EU1-XCAXFEO3-Y, Physica. B, Condensed matter, 205(1), 1995, pp. 81-86
Citations number
10
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
09214526
Volume
205
Issue
1
Year of publication
1995
Pages
81 - 86
Database
ISI
SICI code
0921-4526(1995)205:1<81:FMSOE>2.0.ZU;2-Q
Abstract
Samples of Eu1-xCaxFeO3-y (x = 0.0, 0.2-1.0) were prepared by the soli d state reaction method. X-ray diffraction measurements showed that co mpounds for x < 0.6 have perovskite structure. Three magnetic and one doublet species were observed at room temperature in the Mossbauer spe ctra. The Fe ions are all in a trivalent state. The changes of isomer shift, quadrupole splitting and intensity with composition are discuss ed.