1,12-DIGERMACYCLODOCOSANES - SYNTHESIS, STRUCTURE AND ANION TRANSPORTCAPABILITY

Authors
AOYAGI S OGAWA K TANAKA K TAKEUCHI Y
Citation
S. Aoyagi et al., 1,12-DIGERMACYCLODOCOSANES - SYNTHESIS, STRUCTURE AND ANION TRANSPORTCAPABILITY, Perkin transactions. 2, (2), 1995, pp. 355-358
Citations number
14
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
2
Year of publication
1995
Pages
355 - 358
Database
ISI
SICI code
0300-9580(1995):2<355:1-SSAA>2.0.ZU;2-W
Abstract
An X-ray crystallographic analysis indicated that 1,1,12,12-tetramethy l-1,12-digermacyclodocosane exists exclusively as the [3838] conformer with germanium atoms at corner sites in the crystalline state. The ge ometric parameters of this compound are nicely reproduced by MM3 calcu lations and are found to be comparable with those of relevant carbocyc les. The anion transport capability of 1,12-dichloro-1,12-dimethyl-1,1 2-digermacyclodocosane is much the same with that of the 14-membered- ring analogue.