STRUCTURE AND CONFORMATION OF STEREOISOMERIC C-ISOPROPOXYCARBONYLMETHYLCALIX[4]RESORCINARENES

Authors
BENEDETTI E PEDONE C IACOVINO R BOTTA B DELLEMONACHE G DEROSA MC BOTTA M CORELLI F TAFI A SANTINI A
Citation
E. Benedetti et al., STRUCTURE AND CONFORMATION OF STEREOISOMERIC C-ISOPROPOXYCARBONYLMETHYLCALIX[4]RESORCINARENES, Journal of chemical research. Synopses, (12), 1994, pp. 476-477
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
12
Year of publication
1994
Pages
476 - 477
Database
ISI
SICI code
0308-2342(1994):12<476:SACOSC>2.0.ZU;2-7
Abstract
Treatment of (E)-2,4-dimethoxycinnamic acid isopropyl esters with boro n trifluoride-diethyl ether in chloroform at room temperature affords various stereoisomeric C-alkylcalix[4]resorcinarenes, which differ in their conformations; the crystal structures of two stereoisomers have been determined and compared with geometries resulting from theoretica l calculations.