R. Li et al., LIGHT-SCATTERING IN A (Y PR)BA2CU3O7 SUPERLATTICE AND THE INTENSITY OF A NEW RAMAN-ACTIVE PHONON/, Physica. C, Superconductivity, 242(1-2), 1995, pp. 46-54
In this paper we report Raman results from a high-quality c oriented u
ltra-thin layer (YBa2Cu3O7)(2)/(PrBa2Cu3O7)(1) superconducting superla
ttice. In addition to bulk-like modes a new line is observed at a low
temperature in the region around 320 cm(-1) which is interpreted as or
iginating from the antiphase combination of original IR active B-lu ph
onons in individual YBa2Cu3O7 layers. We explain the Raman intensity o
f such a combined IR mode proposing the mixing of normal vectors and a
n asymmetric crystal field at Y-Pr interfaces.