Ed. Specht et al., THE EFFECT OF COLONIES OF ALIGNED GRAINS ON CRITICAL-CURRENT IN HIGH-TEMPERATURE SUPERCONDUCTORS, Physica. C, Superconductivity, 242(1-2), 1995, pp. 164-168
X-ray microdiffraction has been used to map the orientational distribu
tion of grains in a 4X5 mm(2) polycrystalline film of Tl1-yBa2Cu2Cu3Ox
(Tl-1223) grown on yttria-stabilized zirconia (YSZ). The film consist
s of ''colonies'', each containing similar to 10(4) grains with their
a-axes aligned; the c-axes of all grains are aligned normal to the fil
m, but there is no overall a-axis alignment. While the grain boundarie
s within a colony are small angle, colonies are separated by large-ang
le tilt boundaries. The typical colony size is 0.4 mm. Measured critic
al currents are compared with simulations based on observed distributi
ons of grain alignment; we find that variations in grain alignment acc
ount for the observed variations in the critical current density. Simu
lations over longer distances indicate that a colony structure can sub
stantially increase the critical current, especially in magnetic field
s.