STRUCTURAL ASPECTS OF THE REDOX FLEXIBILITY OF GROUP-VIII METAL-COMPLEXES WITH TRIPODAL POLYPHOSPHINE LIGANDS

Authors
ZANELLO P
Citation
P. Zanello, STRUCTURAL ASPECTS OF THE REDOX FLEXIBILITY OF GROUP-VIII METAL-COMPLEXES WITH TRIPODAL POLYPHOSPHINE LIGANDS, Pure and applied chemistry, 67(2), 1995, pp. 323-330
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
67
Issue
2
Year of publication
1995
Pages
323 - 330
Database
ISI
SICI code
0033-4545(1995)67:2<323:SAOTRF>2.0.ZU;2-K
Abstract
Complexes of transition metal fragments with tripodal polyphosphine li gands (NP3, PP3, triphos) usually display reversible electron-transfer processes. Sometimes, such derivatives undergo electron addition/remo val steps which cause more or less complicated molecular reorganizatio ns. A few examples of these redox-induced rearrangements are here illu strated.