PHOTOCHEMICAL SYNTHESES OF FULLERENE-AMINE ADDUCTS AND THEIR CHARACTERIZATION WITH H-1-NMR SPECTROSCOPY

Authors
INOUE M MACHI L BROWN F INOUE MB FERNANDO Q
Citation
M. Inoue et al., PHOTOCHEMICAL SYNTHESES OF FULLERENE-AMINE ADDUCTS AND THEIR CHARACTERIZATION WITH H-1-NMR SPECTROSCOPY, Journal of molecular structure, 345, 1995, pp. 113-117
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
345
Year of publication
1995
Pages
113 - 117
Database
ISI
SICI code
0022-2860(1995)345:<113:PSOFAA>2.0.ZU;2-E
Abstract
Photoreactions of C-60 With aromatic or aliphatic amines in contact wi th air gave a new type of amine adduct with a general compound formula of C-60(amine)(x)(OH)(y)O-z; the amine was di-2-pyridylamine, morphol ine or N,N-dimethylethylenediamine. The N,N-dimethylethylenediamine ad duct was obtained as a hydrochloride. Its H-1 NMR spectrum showed that the adduct cation, obtained after functionalizing C-60, formed an ion pair with a benzenesulfonate anion.