POWDER ZEEMAN NQR STUDY ON THE ABSORPTION FORMS FOR A NUCLEAR-SPIN OF3 2 - DEPENDENCE ON THE ANGLE BETWEEN THE DIRECTIONS OF AN OSCILLATING MAGNETIC-FIELD AND A STATIC MAGNETIC-FIELD, AND OBSERVATION OF LARGEETA/

Citation
O. Ege et al., POWDER ZEEMAN NQR STUDY ON THE ABSORPTION FORMS FOR A NUCLEAR-SPIN OF3 2 - DEPENDENCE ON THE ANGLE BETWEEN THE DIRECTIONS OF AN OSCILLATING MAGNETIC-FIELD AND A STATIC MAGNETIC-FIELD, AND OBSERVATION OF LARGEETA/, Journal of molecular structure, 345, 1995, pp. 139-144
Citations number
19
Categorie Soggetti
Chemistry Physical
ISSN journal
00222860
Volume
345
Year of publication
1995
Pages
139 - 144
Database
ISI
SICI code
0022-2860(1995)345:<139:PZNSOT>2.0.ZU;2-K
Abstract
As a function of the angle between the directions of the oscillating m agnetic field and the static magnetic field, integral forms of powder Zeeman NQR spectra for a nuclear spin of 3/2 were observed. The powder Zeeman NQR spectra measured for various asymmetry parameters of the e lectric field gradient at nuclei were in good agreement with spectra o btained from computer simulations. The asymmetry parameters of the ele ctric field gradients at the Ga-69 nuclei in GaCl3 and at the Cl-35 nu clei, with one of the two kinds of electronic environment, in BCl3 wer e observed and estimated to give the values 0.85 and 0.42, respectivel y.