DIFFERENCES IN REACTIVITY AND ENANTIOSELECTIVITY IN LIPASE REACTIONS WITH CARBOXYLIC ESTERS AND ALCOHOLS BEARING THE SAME STEREOGENIC CENTER

Authors
SIH JC GU RL
Citation
Jc. Sih et Rl. Gu, DIFFERENCES IN REACTIVITY AND ENANTIOSELECTIVITY IN LIPASE REACTIONS WITH CARBOXYLIC ESTERS AND ALCOHOLS BEARING THE SAME STEREOGENIC CENTER, Tetrahedron : asymmetry, 6(2), 1995, pp. 357-360
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
2
Year of publication
1995
Pages
357 - 360
Database
ISI
SICI code
0957-4166(1995)6:2<357:DIRAEI>2.0.ZU;2-W
Abstract
The reaction rate and stereochemical outcome of lipase reactions obtai ned with carboxylic esters and alcohols, which contain the same stereo genic center, can be modulated by changing the mode of the lipase reac tion, i.e. ester hydrolysis versus alcohol acetylation.