CATALYTIC SYNTHESIS OF (R)-CITRONELLOL AND (S)-CITRONELLOL BY HOMOGENEOUS HYDROGENATION OVER AMIDOPHOSPHINEPHOSPHINITE AND DIAMINODIPHOSPHINE RHODIUM COMPLEXES

Authors
ALI MA ALLAOUD S KARIM A ROUCOUX A MORTREUX A
Citation
Ma. Ali et al., CATALYTIC SYNTHESIS OF (R)-CITRONELLOL AND (S)-CITRONELLOL BY HOMOGENEOUS HYDROGENATION OVER AMIDOPHOSPHINEPHOSPHINITE AND DIAMINODIPHOSPHINE RHODIUM COMPLEXES, Tetrahedron : asymmetry, 6(2), 1995, pp. 369-370
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
2
Year of publication
1995
Pages
369 - 370
Database
ISI
SICI code
0957-4166(1995)6:2<369:CSO(A(>2.0.ZU;2-L
Abstract
The enantioselective production of citronellol (ee = 84 % R and 80 % S ) is performed by hydrogenation of geraniol 1 and nerol 2 over cationi c rhodium complexes modified by amidophosphinephosphinite and diaminod iphosphine chiral ligands.