THE VERTEX CONTRIBUTION TO THE KIRSTE-POROD TERM

Citation
S. Ciccariello et R. Sobry, THE VERTEX CONTRIBUTION TO THE KIRSTE-POROD TERM, Acta crystallographica. Section A, Foundations of crystallography, 51, 1995, pp. 60-69
Citations number
26
Categorie Soggetti
Crystallography
ISSN journal
01087673
Volume
51
Year of publication
1995
Part
1
Pages
60 - 69
Database
ISI
SICI code
0108-7673(1995)51:<60:TVCTTK>2.0.ZU;2-X
Abstract
It is shown that, close to the origin, the correlation function [gamma (r)] of any N-component sample with interfaces made up of planar facet s is always a third-degree polynomial in r. Hence, the only monotonica lly decreasing terms present in the asymptotic expansion of the releva nt small-angle scattered intensity are the Pored [-2 gamma'(0(+))/h(4) ] and the Kirste-Porod [4 gamma((3))(0(+))/h(6)] contributions. The la tter contribution is non-zero owing to the contributions arising from each vertex of the interphase surfaces. The general vertex contributio n is evaluated in closed form and the gamma((3))(0(+)) values relevant to the regular polyhedra are reported.