S. Ciccariello et R. Sobry, THE VERTEX CONTRIBUTION TO THE KIRSTE-POROD TERM, Acta crystallographica. Section A, Foundations of crystallography, 51, 1995, pp. 60-69
It is shown that, close to the origin, the correlation function [gamma
(r)] of any N-component sample with interfaces made up of planar facet
s is always a third-degree polynomial in r. Hence, the only monotonica
lly decreasing terms present in the asymptotic expansion of the releva
nt small-angle scattered intensity are the Pored [-2 gamma'(0(+))/h(4)
] and the Kirste-Porod [4 gamma((3))(0(+))/h(6)] contributions. The la
tter contribution is non-zero owing to the contributions arising from
each vertex of the interphase surfaces. The general vertex contributio
n is evaluated in closed form and the gamma((3))(0(+)) values relevant
to the regular polyhedra are reported.