BINUCLEAR AND POLYMERIC MANGANESE(II) SALICYLATE COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURE AND CATALYTIC ACTIVITY OF [MN-2(HSAL)(4)(H2O)(4)]AND -(H3O)(PY)(4)CENTER-DOT-2PY)(N)](H(2)SAL=SALICYLIC ACID, PY=PYRIDINE)

Authors
DEVEREUX M MCCANN M CASEY MT CURRAN M FERGUSON G CARDIN C CONVERY M QUILLET V
Citation
M. Devereux et al., BINUCLEAR AND POLYMERIC MANGANESE(II) SALICYLATE COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURE AND CATALYTIC ACTIVITY OF [MN-2(HSAL)(4)(H2O)(4)]AND -(H3O)(PY)(4)CENTER-DOT-2PY)(N)](H(2)SAL=SALICYLIC ACID, PY=PYRIDINE), Journal of the Chemical Society. Dalton transactions, (5), 1995, pp. 771-776
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
5
Year of publication
1995
Pages
771 - 776
Database
ISI
SICI code
0300-9246(1995):5<771:BAPMSC>2.0.ZU;2-N
Abstract
The two air-stable manganese(II) salicylate complexes [Mn-2(Hsal)(4)(H 2O)(4)] 1 and polymeric [{Mn-2(sal)(2)(Hsal)(H2O)(H3O)(py)(4).2py}(n)] 2 (H(2)sal = salicylic acid and py = pyridine) have been synthesised easily, and their crystal structures determined. Both contain unsymmet rically bridging salicylate ligands. In the presence of added pyridine 1 and 2 vigorously catalyse the disproportionation of H2O2.