STRUCTURE OF CONOCEPHALENOL, A SESQUITERPENOID ALCOHOL FROM THE EUROPEAN LIVERWORT CONOCEPHALUM-CONICUM - DETERMINATION OF THE ABSOLUTE-CONFIGURATION BY TOTAL SYNTHESIS

Authors
TORI M NAKASHIMA K ASAKAWA Y CONNOLLY JD HARRISON LJ RYCROFT DS SINGH J WOODS N
Citation
M. Tori et al., STRUCTURE OF CONOCEPHALENOL, A SESQUITERPENOID ALCOHOL FROM THE EUROPEAN LIVERWORT CONOCEPHALUM-CONICUM - DETERMINATION OF THE ABSOLUTE-CONFIGURATION BY TOTAL SYNTHESIS, Journal of the Chemical Society. Perkin transactions. I, (5), 1995, pp. 593-597
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
5
Year of publication
1995
Pages
593 - 597
Database
ISI
SICI code
0300-922X(1995):5<593:SOCASA>2.0.ZU;2-T
Abstract
The structure of conocephalenol, a brasilane sesquiterpenoid alcohol i solated from the European liverwort Conocephalum conicum, has been det ermined by extensive NMR studies including a 2D INADEQUATE experiment and by total synthesis, which established the absolute stereochemistry as 1R,9S.