C-13 NMR-SPECTROSCOPY OF UNSATURATED LONG-CHAIN COMPOUNDS - AN EVALUATION OF THE UNSATURATED CARBON SIGNALS AS RATIONAL FUNCTIONS

Authors
Citation
G. Knothe et Mo. Bagby, C-13 NMR-SPECTROSCOPY OF UNSATURATED LONG-CHAIN COMPOUNDS - AN EVALUATION OF THE UNSATURATED CARBON SIGNALS AS RATIONAL FUNCTIONS, Perkin transactions. 2, (3), 1995, pp. 615-620
Citations number
13
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
03009580
Issue
3
Year of publication
1995
Pages
615 - 620
Database
ISI
SICI code
0300-9580(1995):3<615:CNOULC>2.0.ZU;2-C
Abstract
Literature data on the C-13 NMR spectra of unsubstituted monounsaturat ed fatty acids and esters as well as fatty acids and esters with allyl ic hydroxy groups between the double bond and the terminal methyl grou p have been evaluated. The signals of the unsaturated carbons between the functional group at C-1 and the position of shift equivalence (POS E; defined as the location of the double bond where the separations of the olefinic carbon signals becomes zero in unsubstituted compounds) are of special interest because they depend on the distance of the uns aturation from C-1. The resonances of both unsaturated carbons as well as their difference (the shift value of the carbon closer to C-1 is s ubtracted from that of the C closer to the terminal methyl group) are rational functions. The equations for the s are the difference of the equations for the individual unsaturated carbons. When comparing Z and E unsaturation, the equations for s do not differ but those for the i ndividual olefinic carbons differ. Some octadecadienoic acids are also discussed. The results generally agree with the electric field model presented by other authors for explaining the decreases in shift separ ations.