D. Rochat et al., FIELD TRAPPING OF RHYNCHOPHORUS-PHOENICIS WITH STEREOISOMERS OF THE SYNTHETIC AGGREGATION PHEROMONE, Comptes rendus de l'Academie des sciences. Serie 3, Sciences de la vie, 318(2), 1995, pp. 183-190
The attractiveness of different pure or blended stereoisomers of synth
etic aggregation pheromone of the weevil Rhynchophorus phoenicis (3-me
thyl-4-octanol = phoenicol) associated to coconut stem was studied in
field trapping. (3R,4R)-phoenicol (2 mg) was inactive to trap the weev
il whereas (3S,4S)-phoenicol (2 mg) syn-phoenicol (1 mg(3R,4R)- + 1 mg
(3S,4S)-phoenicol) and racemic phoenicol (blend containing 1 mg each
of the 4 stereoisomers) were very attractive to the weevil, with equiv
alent levels. (3S,4S)-Phoenicol, isomer produced by the insect is the
sole active enantiomer of the syn-isomer. The non natural stereoisomer
s did not present any detectable inhibitory effect Agricultural use of
synthetic phoenicol and the role of chirality in the specificity of p
heromone communication in Rhynchophorus phoenicis are discussed.