Da. Sadler et D. Littlejohn, AUTOMATIC WAVELENGTH CALIBRATION PROCEDURE FOR USE WITH AN OPTICAL SPECTROMETER AND ARRAY DETECTOR, Journal of analytical atomic spectrometry, 10(3), 1995, pp. 253-257
Echelle spectrometers with cross-dispersion ate often used in emission
spectroscopy owing to their high spectral resolution and good light t
hroughput. The resultant two-dimensional dispersion plane is ideally s
uited to array detectors such as the charge-injection device (CID) or
charge-coupled device (CCD). The successful coupling of an echelle spe
ctrometer with an array detector permits true simultaneous spectroscop
y to be performed over a large spectral range. In order to correctly i
dentify spectral features it is necessary to have an accurate waveleng
th calibration function which maps the CCD/CID pixel co-ordinates to w
avelength. A new approach to the wavelength calibration of optical spe
ctrometers with array detection is proposed that does not involve a di
rect modelling of the spectrometer dispersion. Instead, the difference
between an ideal conceptual spectrometer and the physical instrument
is modelled. The procedure is able to compensate for the effects of ma
nufacturing tolerances and local temperature and pressure conditions.
Preliminary results, obtained by simulation with a computer-modelled e
chelle spectrometer, has shown that a sub-pixel accuracy in the predic
ted position of spectral lines can be achieved over a temperature rang
e 5-35 degrees C.