S(RN)1 SYNTHESIS OF VIC-DINITRO COMPOUNDS CONTAINING A NITRODIOXANE SUBUNIT

vic-Dinitro compounds containing a nitrodioxane subunit can be obtaine d by S(RN)1; reactions between either open chain gem-chloronitro deriv atives as substrates and an anion from nitrodioxane as the nucleophile or 'reversed' reagents namely gem-chloronitrodioxane (substrate) and anions from nitro derivatives. The former access is more efficient and is rationalized on the basis that the structure of the radical anion generated by mono electron transfer to the respective substrates allow s an appropriate choice of reagents for optimizing the yield of the ti tle compounds to be made.