A NEW CATALYTIC TRANSFORMATION OF DIAZO ESTERS - HYDRIDE ABSTRACTION IN DIRHODIUM(II)-CATALYZED REACTIONS

Authors
DOYLE MP DYATKIN AB AUTRY CI
Citation
Mp. Doyle et al., A NEW CATALYTIC TRANSFORMATION OF DIAZO ESTERS - HYDRIDE ABSTRACTION IN DIRHODIUM(II)-CATALYZED REACTIONS, Journal of the Chemical Society. Perkin transactions. I, (6), 1995, pp. 619-621
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
6
Year of publication
1995
Pages
619 - 621
Database
ISI
SICI code
0300-922X(1995):6<619:ANCTOD>2.0.ZU;2-4
Abstract
Secondary benzylic and allylic diazoacetates undergo dirhodium(II)-cat alysed diazo decomposition to form, competitively or exclusively, keto ne and vinylidene products from intramolecular hydride abstraction in catalyst ligand-dependent molar ratios.