SYNTHESIS AND CHARACTERIZATION OF SOME MIXED ALKYL-CARBAMATES OF ZINCOR CADMIUM - CRYSTAL-STRUCTURES OF [ZN(4)ME(2)(O(2)CNET(2))(6)] AND [ZN(4)ME(4)(O(2)CNET(2))(4)]

Authors
ABRAHAMS I MALIK MA MOTEVALLI M OBRIEN P
Citation
I. Abrahams et al., SYNTHESIS AND CHARACTERIZATION OF SOME MIXED ALKYL-CARBAMATES OF ZINCOR CADMIUM - CRYSTAL-STRUCTURES OF [ZN(4)ME(2)(O(2)CNET(2))(6)] AND [ZN(4)ME(4)(O(2)CNET(2))(4)], Journal of the Chemical Society. Dalton transactions, (6), 1995, pp. 1043-1046
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
6
Year of publication
1995
Pages
1043 - 1046
Database
ISI
SICI code
0300-9246(1995):6<1043:SACOSM>2.0.ZU;2-3
Abstract
Some mixed alkyl-carbamates of formula [M(4)R(2)(O(2)CNEt(2))(6)] (M = Zn, R = Me or Et; M = Cd, R = Me) have been synthesized and character ized. The single crystal structure of [Zn(4)Me(2)(O(2)CNEt(2))(6)] con sists of an unusual tetranuclear molecule with a plane of zinc atoms. The compound [Zn(4)Me(4)(O(2)CNEt(2))(4)] has also been prepared. Its structure is based on an approximately tetrahedral arrangement of zinc atoms.