ELECTROPHILIC REACTIVITY OF ARENE CARBONYL CLUSTER COMPLEXES WITH THERU6C CORE - CRYSTAL AND MOLECULAR-STRUCTURE OF [RU6C(CO)(14)(ETA(6)-C(6)H(4)PH(2)-1,4)]

Authors
BORCHERT T LEWIS J PRITZKOW H RAITHBY PR WADEPOHL H
Citation
T. Borchert et al., ELECTROPHILIC REACTIVITY OF ARENE CARBONYL CLUSTER COMPLEXES WITH THERU6C CORE - CRYSTAL AND MOLECULAR-STRUCTURE OF [RU6C(CO)(14)(ETA(6)-C(6)H(4)PH(2)-1,4)], Journal of the Chemical Society. Dalton transactions, (6), 1995, pp. 1061-1062
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
6
Year of publication
1995
Pages
1061 - 1062
Database
ISI
SICI code
0300-9246(1995):6<1061:EROACC>2.0.ZU;2-1
Abstract
Addition of LiPh to Ru6C(CO)(12)(eta(6)-C6H6)(mu-eta(2):eta(2)-C6H8)], 11)(eta(6)-C6H6)(mu(3)-eta(2):eta(2):eta(2)-C6H6)] and [RU(6)C(CO)(14 )(eta(6)-C6H6)], followed by treatment with [CPh(3)][BF4], has led to the substituted arene cluster complexes O)(12)(mu-eta(2):eta(2)-C6H6)( eta(6)-C(6)H(5)Ph)], -eta(2):eta(2):eta(2)-C6H6)(eta(6)-C(6)H(5)Ph)]an d [Ru6C(CO)(14)(eta(6)-C(6)H(4)Ph(2)-1,4)] (structure established by X -ray crystallography).