Radiation resulting from interaction between the effluent cloud of a s
pace shuttle thruster and the ambient atmosphere was observed with a s
pectrograph aboard the shuttle. The spectral measurements were made be
tween 400 and 800 nm with a resolution of 3 nm. The primary emissions
are identified as NO2, HNO, O(D-1), and O(S-1). These are the first ob
servations of O(S-1) emission in the shuttle plume. These data are com
pared with previous measurements, and possible excitation mechanisms a
re discussed. The results are also compared with a Monte Carlo simulat
ion of thruster plume-atmosphere interaction radiation.