NICKEL L-EDGE X-RAY-ABSORPTION STUDY OF NICKEL PHOSPHINE HALIDE-COMPLEXES

Citation
Mj. Ashcroft et al., NICKEL L-EDGE X-RAY-ABSORPTION STUDY OF NICKEL PHOSPHINE HALIDE-COMPLEXES, Physica. B, Condensed matter, 209(1-4), 1995, pp. 725-726
Citations number
2
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
09214526
Volume
209
Issue
1-4
Year of publication
1995
Pages
725 - 726
Database
ISI
SICI code
0921-4526(1995)209:1-4<725:NLXSON>2.0.ZU;2-B
Abstract
Nickel L(III,II) absorption spectra of [NiX(2)P(2)] or [NiX(2)(P-P)] ( where X = Cl, Br and P = PEt(3), PPh(3) and P-P = dppe) are shown to b e very sensitive to the local Ni environment and able to differentiate between tetrahedral, cis-square planar and trans-square planar geomet ries.