Ic. Baldwin et Jmj. Williams, ALPHA-AMINOPHOSPHONATE DERIVATIVES AS NUCLEOPHILES IN DIASTEREOSELECTIVE AND ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION-REACTIONS, Tetrahedron : asymmetry, 6(3), 1995, pp. 679-682
The palladium catalysed reaction between allyl acetates and Schiff bas
e derivatives of alpha-aminophosphonates is reported. For suitable sub
strates, the observed diastereoselectivities (up to 87:13) and enantio
selectivities (>96% eel are high.