ALPHA-AMINOPHOSPHONATE DERIVATIVES AS NUCLEOPHILES IN DIASTEREOSELECTIVE AND ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION-REACTIONS

Authors
BALDWIN IC WILLIAMS JMJ
Citation
Ic. Baldwin et Jmj. Williams, ALPHA-AMINOPHOSPHONATE DERIVATIVES AS NUCLEOPHILES IN DIASTEREOSELECTIVE AND ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION-REACTIONS, Tetrahedron : asymmetry, 6(3), 1995, pp. 679-682
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
3
Year of publication
1995
Pages
679 - 682
Database
ISI
SICI code
0957-4166(1995)6:3<679:ADANID>2.0.ZU;2-R
Abstract
The palladium catalysed reaction between allyl acetates and Schiff bas e derivatives of alpha-aminophosphonates is reported. For suitable sub strates, the observed diastereoselectivities (up to 87:13) and enantio selectivities (>96% eel are high.