TOTAL CHIRALITY TRANSFER IN PALLADIUM(0)-CATALYZED REARRANGEMENT OF SILICON SUBSTITUTED VINYLOXIRANES

Authors
LEBIDEAU F AUBERT C MALACRIA M
Citation
F. Lebideau et al., TOTAL CHIRALITY TRANSFER IN PALLADIUM(0)-CATALYZED REARRANGEMENT OF SILICON SUBSTITUTED VINYLOXIRANES, Tetrahedron : asymmetry, 6(3), 1995, pp. 697-700
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
3
Year of publication
1995
Pages
697 - 700
Database
ISI
SICI code
0957-4166(1995)6:3<697:TCTIPR>2.0.ZU;2-S
Abstract
The palladium(0)-catalyzed rearrangement of silylated vinyloxiranes oc curs with a total transfer of chirality. The absolute stereochemistry of the aldehyde has been determined.