ASYMMETRIC CATALYTIC REDUCTION OF CARBONYL-COMPOUNDS USING C-2 SYMMETRICAL DIAMINES AS CHIRAL LIGANDS

Authors
GAMEZ P FACHE F LEMAIRE M
Citation
P. Gamez et al., ASYMMETRIC CATALYTIC REDUCTION OF CARBONYL-COMPOUNDS USING C-2 SYMMETRICAL DIAMINES AS CHIRAL LIGANDS, Tetrahedron : asymmetry, 6(3), 1995, pp. 705-718
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
3
Year of publication
1995
Pages
705 - 718
Database
ISI
SICI code
0957-4166(1995)6:3<705:ACROCU>2.0.ZU;2-Q
Abstract
The catalytic asymmetric reduction of prochiral ketones by hydride tra nsfer using various C-2 symmetric chiral diamines as ligands and rhodi um complexes is studied. Kinetic studies show an increase of the enant iomeric excess with the conversion.