SPECTRA OF CARBANIONS FORMED FROM ALLYL CYANIDE DURING ISOMERIZATION IN ZEOLITE NAY-FAU WITH STRONG BASIC SITES

Authors
HANNUS I FORSTER H TASI G KIRICSI I MOLNAR A
Citation
I. Hannus et al., SPECTRA OF CARBANIONS FORMED FROM ALLYL CYANIDE DURING ISOMERIZATION IN ZEOLITE NAY-FAU WITH STRONG BASIC SITES, Journal of molecular structure, 348, 1995, pp. 345-348
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
348
Year of publication
1995
Pages
345 - 348
Database
ISI
SICI code
0022-2860(1995)348:<345:SOCFFA>2.0.ZU;2-8
Abstract
Double bond isomerization of allyl cyanide to crotononitrile over a ba sic zeolite catalyst was monitored by IR and UV-VIS spectroscopy in or der to get information on the surface intermediates involved. Due to t he spectral changes the occurence of a carbanionic intermediate seems to be highly probable characterized by an absorption at 400 nm.