The technique of electroless chemical deposition was used for preparat
ion of thin solid films of lead sulfide (PbS). The thin solid PbS film
s were deposited on a glass substrate previously coated with a very th
in layer of Cu2S. The optimal temperature of deposition was between 34
3 and 363 K. The thickness of these films was controled by changing th
e concentration of the reaction solutions and the deposition time. The
optical properties of these thin solid films of different thickness w
ere determined by means of near infrared spectroscopy, Raman spectrosc
opy and visible spectroscopy.