ULTRAFAST COLLISIONAL REDISTRIBUTION OF VIBRATIONAL-ENERGY IN SMALL POLYATOMIC-MOLECULES

Authors
KOSTEREV AA MALINOVSKY AL RYABOV EA
Citation
Aa. Kosterev et al., ULTRAFAST COLLISIONAL REDISTRIBUTION OF VIBRATIONAL-ENERGY IN SMALL POLYATOMIC-MOLECULES, Journal of molecular structure, 349, 1995, pp. 231-233
Citations number
4
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
349
Year of publication
1995
Pages
231 - 233
Database
ISI
SICI code
0022-2860(1995)349:<231:UCROVI>2.0.ZU;2-2
Abstract
The rate constants of energy relaxation are measured for high-frequenc y vibrations in CHF3 and CHF2Cl in gas phase. The obtained values are extraordinarily high for V-V' exchange. The measurements carried out i n gas mixtures with different buffer gases unambiguously show a predom inant role of collision-induced intramolecular redistribution.