Jb. Ma et Dc. Sherrington, PREPARATION OF POLYMER-SUPPORTED PALLADIUM(II) COMPLEXES AND USE IN ANTI-MARKOVNIKOV WACKER OXIDATIONS OF OCT-1-ENE TO OCTANAL IN TERT-BUTYL ALCOHOL, Journal of chemical research. Synopses, (4), 1995, pp. 119-119
Cyanomethylated and carboxymethylated crosslinked polystyrene resin su
pports, prepared by appropriate chemical modification of a chloromethy
lated polystyrene support, have been used to immobilize Pd(II) complex
es which in turn have been used as catalysts in aerobic Wacker oxidati
ons of oct-1-ene in tert-butyl alcohol at 60-degrees-C.