HIGHLY STEREOSELECTIVE FORMATION OF OPTICALLY PURE 2,4-OXAZOLIDINEDIONE VIA DIASTEREOSELECTIVE DIHYDROXYLATION OF STITUTED-2'-PROPENOYL)-4-ISOPROPYL-2-OXAZOLIDINONE

Authors
SONG CE ROH EJ LEE SG KIM IO
Citation
Ce. Song et al., HIGHLY STEREOSELECTIVE FORMATION OF OPTICALLY PURE 2,4-OXAZOLIDINEDIONE VIA DIASTEREOSELECTIVE DIHYDROXYLATION OF STITUTED-2'-PROPENOYL)-4-ISOPROPYL-2-OXAZOLIDINONE, Tetrahedron : asymmetry, 6(4), 1995, pp. 871-872
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
4
Year of publication
1995
Pages
871 - 872
Database
ISI
SICI code
0957-4166(1995)6:4<871:HSFOOP>2.0.ZU;2-4
Abstract
Catalytic asymmetric dihydroxylation (ADH) of S)-3-((E)-3'-substituted -2'-propenoyl)-4-isopropyl -2-oxazolidinone 1a and 1b resulted in the in situ rearrangement of the initially produced diols or its osmates t o provide pyI-2'-hydroxyethyl)-5(S)-5((1'R)-1'-hydroxybenzyl (2a) and -hydroxyethyl (2b))-2,4-oxazolidinedione, respectively. The structure of 2a was determined by X-ray crystal structure analysis.