COORDINATION CHEMISTRY OF ADPO

Authors
ARDUENGO AJ DIAS HVR CALABRESE JC
Citation
Aj. Arduengo et al., COORDINATION CHEMISTRY OF ADPO, Phosphorus, sulfur and silicon and the related elements, 87(1-4), 1994, pp. 1-10
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
87
Issue
1-4
Year of publication
1994
Pages
1 - 10
Database
ISI
SICI code
1042-6507(1994)87:1-4<1:CCOA>2.0.ZU;2-0
Abstract
The hypervalent phosphorous compound, ,8-dioxa-1-phosphabicyclo-3.3.0 octa-2,4,6-triene (ADPO) forms adducts with chromium, tungsten, nicke l and palladium metal centers. All four new adducts contain tetrahedra l phosphorous atoms as a result of folding the ADPO unit. Tis folding of the planar 10-P-3 ADPO and 8-P-3 ADPO and the strength of the phosp horous-metal interaction. In the case of a homoleptic palladium(II) co mplex, dimerization of the coordinated ADPO unit was observed.