SYNTHESIS OF TRIPODAL TRIPHOSPHINES AND THEIR DERIVATIVES

Authors
MILLS JL HARWELL DE DEMARQUIS VK MARX JN
Citation
Jl. Mills et al., SYNTHESIS OF TRIPODAL TRIPHOSPHINES AND THEIR DERIVATIVES, Phosphorus, sulfur and silicon and the related elements, 87(1-4), 1994, pp. 149-156
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
87
Issue
1-4
Year of publication
1994
Pages
149 - 156
Database
ISI
SICI code
1042-6507(1994)87:1-4<149:SOTTAT>2.0.ZU;2-R
Abstract
A general strategy for the synthesis of a series of tripodal triphosph ines XC[(CH2)(n)PR(2)](3) (where X = H or Me, n = 1-4) has been sought . Particular emphasis has been placed on attempts to synthesize a seri es member XC[(CH2)(n+1)PR(2)](3) from its precursor XC[(CH2)(n)PR(2)]( 3). We will present the results of our synthetic efforts, together wit h the characterization of a number of new tripodal triphosphines and t heir derivative oxides. Some ''ether-legged'' tripodal triphosphines h ave also been synthesized.