THE ELECTRIC-CONDUCTIVITY OF LIQUID CESIUM TO HIGH-TEMPERATURES

Citation
E. Keller et Eu. Franck, THE ELECTRIC-CONDUCTIVITY OF LIQUID CESIUM TO HIGH-TEMPERATURES, Berichte der Bunsengesellschaft fur Physikalische Chemie, 99(4), 1995, pp. 682-684
Citations number
21
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
ISSN journal
00059021 → ACNP
Volume
99
Issue
4
Year of publication
1995
Pages
682 - 684
Database
ISI
SICI code
0005-9021(1995)99:4<682:TEOLCT>2.0.ZU;2-5
Abstract
An apparatus is used with a thin walled stainless steel cell and a fou r-pole potentiometric arrangement to perform precise measurements of t he electric conductivity sigma of liquid cesium to high temperatures a t equilibrium vapour pressure. Results are given from 200 to 800 degre es C. A five-parameter equation for use from the melting temperature o f 28.4 degrees C to 1200 degrees C is presented. Conductivity values o f 17705 and 6435 ohm(-1) cm(-1) were obtained for 200 and 800 degrees C, respectively. The relative expected error is given in dependence of temperature. A typical value is +/- 0.34%. All data are well within t he range of validity of the near-free-electron, NFE, model for metalli c conductance.