SYNTHESIS AND GAS-CHROMATOGRAPHIC MASS-SPECTROMETRIC STUDY OF SILYLATED HYDROXYQUINONES ON ALL HYDROXYL-GROUPS

Authors
BAKOLACHRISTIANOPOULOU MN PAPAGEORGIOU VP APAZIDOU KK
Citation
Mn. Bakolachristianopoulou et al., SYNTHESIS AND GAS-CHROMATOGRAPHIC MASS-SPECTROMETRIC STUDY OF SILYLATED HYDROXYQUINONES ON ALL HYDROXYL-GROUPS, Phosphorus, sulfur and silicon and the related elements, 88(1-4), 1994, pp. 53-65
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
88
Issue
1-4
Year of publication
1994
Pages
53 - 65
Database
ISI
SICI code
1042-6507(1994)88:1-4<53:SAGMSO>2.0.ZU;2-M
Abstract
Complete silylation of all hydroxyl groups of hydroxyquinones is repor ted to be effectively carried out using N-methyl-N-trimethylsilyl-trif luoroacetamide (MSTFA). The silylated products are studied by gas chro matography/mass spectrometry. A detailed study of their mass spectra p rovides data for the elucidation of their fragmentation mechanisms as well as the deduction of the hydroxy-group position in the hydroxyquin one backbone.