C. Mundt et L. Riesel, N-PHOSPHANYLATED 1.3.2-OXAZAPHOSPHOLANES AND 1.3.2-DIAZAPHOSPHOLANES AND 1.3.2-DIAZAPHOSPHORINANES, Phosphorus, sulfur and silicon and the related elements, 88(1-4), 1994, pp. 75-81
The formation of the N-phosphanyl derivatives of the oxaza- and diazap
hosphorinanes and -phospholanes 2-10 by the reaction of PX(3) (X = Cl,
Br) with alcoholamines and diamines is described. The unusually large
(2)J(PNP) coupling constants of the products are discussed.