ON DERIVATIZATION REACTIONS OF LORO-3-DICHLOROPHOSPHANYL-1.3.2-OXAZAPHOSPHORINANE

Authors
MUNDT C RIESEL L
Citation
C. Mundt et L. Riesel, ON DERIVATIZATION REACTIONS OF LORO-3-DICHLOROPHOSPHANYL-1.3.2-OXAZAPHOSPHORINANE, Phosphorus, sulfur and silicon and the related elements, 88(1-4), 1994, pp. 169-177
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
88
Issue
1-4
Year of publication
1994
Pages
169 - 177
Database
ISI
SICI code
1042-6507(1994)88:1-4<169:ODROL>2.0.ZU;2-Q
Abstract
Derivatisation reactions of loro-3-dichlorophosphanyl-1.3.2-oxazaphosp horinane 1b with protic nucleophiles like HNEt(2), C2H5OH, CH3OH and t he Franz-reagent NEt(3)3HF forming the substituted N-phosphanylphospho rinanes 2-10 are described. Furthermore the temperature dependence of the (2)J(PNP)-coupling constant of loro-3-dichlorophosphanyl-1.3.2-oxa zaphosphorinane 1b and s(diethylamino)phosphanyl-1.3.2-oxazaphosphorin ane 2 in a range from 203 K to 353 K was investigated.